1)
How @ User Defined SIF at TEE ?
Yes, you set that Configuration Directive to "True". Then you can define the SIF on the "SIF & Tee" dialog. You define an SIF on any node using this dialog. The reason for the Configuration Directive is that (usually) you're overriding a "Code Defined" value, so this acts as a check - it makes you think about what you're doing.
2)
c2 still not showing USER DEFINED SIF in "Environment" Module, to review the SIF at Bend.
Correct, that scratchpad shows the "Code" computed values only. Your specified value will be shown in the output.
Do we need to configure some option or is it BUG in c2?
This is not a bug. The scratchpad allows you to alter data and recompute an SIF. The scratchpad doesn't care about any SIF you specified.