You should consider induction heating on the molten sulfur line. It's a lot cheaper than a full jacket. Some vendors also provide full contact steam tracing with, essentially, channels with a cover seal plate rolled to match the pipe OD. These can be used singly or multiply - the advantage is that it requires two failures in order for steam and smlten sulfur to come in contact.
Both these systems are relatively new technology, but have some service time. Also, they provide very little stiffness above that of the core line, so your piping system can be more flexible.
Cleaning a sleeve-type expansion joint is not terrible, install it near a tee where the flow turns and goes out the branch, and put a blind flange on the other end of the tee. Then you can remove the blind flange and rod out the expansion joint.
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CraigB