First of all ensure that your work is being well checked as any misktakes with 300 C steam can have deadly consequences.
Caesar is likely referencing Z662 4.8.4, 4.8.5 or 4.7.1 when asking for the T factor to determine the maximum allowable stress whereas Clause 14 directs the designer to look to B31.3 for guidence. 14.2.5.1 references B31.3 319.1 to 321.4. Clause 14.2.5.2 b) directs the analyst to "use of an appropriate method of stress analysis so that stress levels do not exceed those allowed by B31.3."
As well if you are designing using the rules in Annex I you must follow some of the high pressure piping B31.3 IX rules as outlined in I.2.3.1 and I.2.3.2 and I.2.4.
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