Thanks Bob,
As I am getting from your reply you are considering more as B31.3 case with a bit of severity in terms of connecting to a boiler(which I do agree as well)
The point for our process people is that they want to consider whatever produces steam as "power boiler" especially when they sell it as biproduct and therefore scope of ASME I;consequently B31.1 would be applicable.(by the way the position of valve is after superheater and this may end up to take the whole steam drum to superheater piping and a bit of superheater outlet as B31.1)
My argue is when whole plant is B31.3 application and we have couple of equipment items, even though producing steam, but part of the stream of petrochemical production, I take it as a case that B31.3 dominates it. Hence the equipment would be ASME VIII and piping would be (as you say) either SA material designed by piping or B31.3, rather than ASME I and the hassle of variety of commodities for identical composition BUT B31.1 and B31.3, concerns of matching them stressing them as two calcs or one,etc.
thoughts are very welcome.