Hmmmn. How did it fail? What were the symptoms and the environment? High vibration? Extra-long service maybe? Any chance it (the joint) might have been abused (by accident) or an "undeclared" high side load from shock, impact from a crane load or nearby construction?
http://pipespecialties.com/pdf/FP196A.pdfThat's a writeup for Cl 7000 flanges - nothing really stands out as unusual or different about the installation that would cause a problem: torque limts and stud assembly requirements are not out-of-the-ordinary, for example.
One other story on-line about Bondstrand 7000M says its good for 121 deg C max operating temperature, so your 115 deg "violation" of a 93 deg C spec isn't even out-of-range for the material.
http://www.bondstrand-marine.com/_DOWNLOADS/PDF/FP918.pdfThe second source has technical spec's and material properties for the "pipe" and max span limits based on 21 deg C properties - but it didn't say anything (I saw at least) about maximum "side loads" allowed on the flanges joining two random sections of the pipe.